I just don't like having this stupid dilemma now where I'm like, should I play this now on PS5 or wait for the superior PC port?
From my experience: if a game is so good I'm interested in, I just play it where it comes first (unless it's like a month or two apart). I have double dipped so many times and never finished a game on PC that I finished before on PS4/PS5. Even with all the blows and whistles it's often not worth going through again, except for it's an exceptionally good game. But even that, depending on the game's nature it might not be well-suited for another playthrough, and I rather play something new with my limited time instead.
even RDR2, God of War, etc. which I loved I didn't manage to play again on PC for more than a few hours. Some games I stopped buying then for PC.
So you must decide whether the game itself is interesting enough for you, not the performance and visuals. If it's the latter you're interested in, you can easily wait. If it's a really great game and you want it now, you'll enjoy it thoroughly despite having slightly worse visuals and performance than it could have on PC in 2 or 3 years time.
Also, that's just personally though, I love the DualSense and the complete haptics package it delivers in supporting games. Unfortunately many, while having a PC version of a game, doesn't support it there.
so my scheme is as follows:
AA(A) title at least 40fps mode and full DualSense support: PS5 version.
AA(A) that looks and runs vastly better on PC and doesn't use the DualSense's new features: PC version.
(smaller) Indie titles: PC version so I could always play them on the Deck.
There are exceptions: some games doesn't support all DualSense features, but run better console because incompetent developers can't figure out DX12/UE stutter on PC. That's the PS5 version then for me as well, regardless of PC graphics. I can't enjoy a game that stutters all the time so I couldn't care less about visuals or overall FPS.
So if in doubt, I'll try the PC version first, refund if I'm not satisfied, look for videos on the console version and go for that one.
If there's no PC version at all: PS5 version.
Once done once or twice it's really easy and not that big of a dilemma.